Recent Progress and Perspectives in the Electrokinetic Characterization of Polyelectrolyte Films
نویسندگان
چکیده
The analysis of the charge, structure and molecular interactions of/within polymeric substrates defines an important analytical challenge in materials science. Accordingly, advanced electrokinetic methods and theories have been developed to investigate the charging mechanisms and structure of soft material coatings. In particular, there has been significant progress in the quantitative interpretation of streaming current and surface conductivity data of polymeric films from the application of recent theories developed for the electrohydrodynamics of diffuse soft planar interfaces. Here, we review the theory and experimental strategies to analyze the interrelations of the charge and structure of polyelectrolyte layers supported by planar carriers under electrokinetic conditions. To illustrate the options arising from these developments, we discuss experimental and simulation data for plasma-immobilized poly(acrylic acid) films and for a polyelectrolyte bilayer consisting of poly(ethylene imine) and poly(acrylic acid). Finally, we briefly outline potential future developments in the field of the electrokinetics of polyelectrolyte layers.
منابع مشابه
Steel Coated with Cationic Poly (Ethylenimine) (PEI) and Anionic Poly (Vinylsulfate) (PVS) Polyelectrolyte Multilayer Nanofilm with Different Benzotriazole Inhibitor Concentrations
Nano-films consisting of an alternating sequence of positively and negatively charged polyelectrolyteshave been prepared by means of the electrostatic layer-by-layer sequential assembly technique on mildsteels. The mild steels were pretreated electrochemically to modify the mild steel surface. The modificationof the mild steel surface resulted in increasing the adhesion of the obtained nano-fil...
متن کاملFabrication and Characterization of Chitosan/Alginate Multilayer Composite Membrane Supported by a Porous Poly (Acrylonitrile) Substrate for Pervaporation Dehydration of Alcohol
Chitosan (CS) and alginate (Alg) are complementary in their membrane performance, but the combination of them is normally difcult to use due to their different solubilities. Layer-by-Layer deposition appears to be an effective method for improving the separation efciency of a composite membrane. In this work, the polyelectrolyte multilayer composite membranes (PEMCMs) wer...
متن کاملFormation of Needle Like Hydroxyl Apatite by Polyelectrolyte-modified Inverse Microemulsion Technique
In this work needle like hydroxy apatite were synthesized in a reverse microemulsion droplets of water in cyclohexane, separated by a cationic surfactant and co-surfactant, in the presence of Na-polyacrylate (PAA) as an anionic polyelectrolyte. Characterization of the as formed HAp nanoparticles at the room temperature were carried out by X-ray diffraction (XRD) and Fourier transform infrared s...
متن کاملFormation of Needle Like Hydroxyl Apatite by Polyelectrolyte-modified Inverse Microemulsion Technique
In this work needle like hydroxy apatite were synthesized in a reverse microemulsion droplets of water in cyclohexane, separated by a cationic surfactant and co-surfactant, in the presence of Na-polyacrylate (PAA) as an anionic polyelectrolyte. Characterization of the as formed HAp nanoparticles at the room temperature were carried out by X-ray diffraction (XRD) and Fourier transform infrared s...
متن کاملCharacterization and Corrosion Behavior of Hydroxyapatite- Coated Titanium Substrates Prepared Through Laser Induced Liquid Deposition Technique
Titanium and titanium alloys are often used in orthopedic surgery and dentistry because of their especial characteristics such as biocompatibility, mechanical properties, and corrosion resistance. However, their bio- inertness is the most serious drawback for biomedical applications. Therefore, a bioactive coating like hydroxyapatite (HA) is coated on their surface. In this regard, in the prese...
متن کامل